dc.contributor.author | Karaca, EO | |
dc.contributor.author | Gurbuz, N | |
dc.contributor.author | Ozdemir, I | |
dc.contributor.author | Doucet, H | |
dc.contributor.author | Sahin, O | |
dc.contributor.author | Buyukgungor, O | |
dc.contributor.author | Cetinkaya, B | |
dc.date.accessioned | 2022-03-28T12:23:31Z | |
dc.date.available | 2022-03-28T12:23:31Z | |
dc.date.issued | 2015 | |
dc.identifier.uri | http://hdl.handle.net/11616/58427 | |
dc.description.abstract | The synthesis and characterization of novel 1,3-benzyl-3,4,5,6-tetrahydropyrimidin-2-ylidene-based N-hetero-cyclic carbene palladium(II) complexes (1a-d) were described. The crystal structure of trans-dichlorobis[1,3-bis(4-methylbenzyl)-3,4,5,6-tetrahydropyrimidin-2-ylidend- palladium(II) was presented. Pd(II) complexes 1a-d were tested as catalysts in the direct C5 or C2 arylation of furans, thiophenes, and thiazoles, with various aryl bromides at 150 degrees C for 1 h. These complexes exhibited moderate to high catalytic activities under the given conditions. | |
dc.source | ORGANOMETALLICS | |
dc.title | Palladium Complexes with Tetrahydropyrimidin-2-ylidene Ligands: | |
dc.title | Catalytic Activity for the Direct Arylation of Furan, Thiophene, and | |
dc.title | Thiazole Derivatives |
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