Palladium Complexes with Tetrahydropyrimidin-2-ylidene Ligands:

dc.contributor.author	Karaca, EO
dc.contributor.author	Gurbuz, N
dc.contributor.author	Ozdemir, I
dc.contributor.author	Doucet, H
dc.contributor.author	Sahin, O
dc.contributor.author	Buyukgungor, O
dc.contributor.author	Cetinkaya, B
dc.date.accessioned	2022-03-28T12:23:31Z
dc.date.available	2022-03-28T12:23:31Z
dc.date.issued	2015
dc.identifier.uri	http://hdl.handle.net/11616/58427
dc.description.abstract	The synthesis and characterization of novel 1,3-benzyl-3,4,5,6-tetrahydropyrimidin-2-ylidene-based N-hetero-cyclic carbene palladium(II) complexes (1a-d) were described. The crystal structure of trans-dichlorobis[1,3-bis(4-methylbenzyl)-3,4,5,6-tetrahydropyrimidin-2-ylidend- palladium(II) was presented. Pd(II) complexes 1a-d were tested as catalysts in the direct C5 or C2 arylation of furans, thiophenes, and thiazoles, with various aryl bromides at 150 degrees C for 1 h. These complexes exhibited moderate to high catalytic activities under the given conditions.
dc.source	ORGANOMETALLICS
dc.title	Palladium Complexes with Tetrahydropyrimidin-2-ylidene Ligands:
dc.title	Catalytic Activity for the Direct Arylation of Furan, Thiophene, and
dc.title	Thiazole Derivatives

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