| dc.contributor.author | Cetinkaya, B. | |
| dc.contributor.author | Hitchcock, P.B. | |
| dc.contributor.author | Lappert, M.F. | |
| dc.contributor.author | Smith, R.G. | |
| dc.date.accessioned | 2022-10-06T09:30:36Z | |
| dc.date.available | 2022-10-06T09:30:36Z | |
| dc.date.issued | 1992 | |
| dc.identifier.issn | 00224936 (ISSN) | |
| dc.identifier.uri | http://hdl.handle.net/11616/62766 | |
| dc.description.abstract | The first neutral, mononuclear 4f thiolates, [Sm(SAr)3] 1 and [Yb(SAr)2(dme)2] 2, have been prepared, and X-ray characterised [<Sm-S> 2.645(9) Å, <Yb-S> 2.756(8) Å], 1 from [Sm(CHR′2)3] + 3ArSH and 2 from [Yb(NR′2)2(dme)2] [obtained from Yb + Sn(NR′2)2]; 1 was not readily accessible from ArSH and Yb in liquid NH3, although replacing ArSH by Ar′OH yielded [Yb(OAr′)2(thf)3] [Ar = C6H 2But3-2,4,6; Ar′ = C6H 2But2-2,6-Me-4; R′ = SiMe 3′ dme = (MeOCH2)2, thf = OC 4H8]. | |
| dc.source | Journal of the Chemical Society, Chemical Communications | |
| dc.title | The first neutral, mononuclear 4f metal thiolates and new methods for corresponding aryl oxides and bis(trimethylsilyl)amides |
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