dc.contributor.author |
Temel, H |
|
dc.contributor.author |
Pasa, S |
|
dc.contributor.author |
Ocak, YS |
|
dc.contributor.author |
Yilmaz, I |
|
dc.contributor.author |
Demir, S |
|
dc.contributor.author |
Ozdemir, I |
|
dc.date.accessioned |
2022-10-19T07:36:45Z |
|
dc.date.available |
2022-10-19T07:36:45Z |
|
dc.date.issued |
2012 |
|
dc.identifier.uri |
http://hdl.handle.net/11616/81279 |
|
dc.description.abstract |
The thio Schiff base ligand N,N'-bis(o-hydroxy-1-naphtaldehydene)-1,2-bis(o-amino phenilthio)ethane (L) was synthesized by the condensation of o-hydroxy-1-naphthaldehyde and 1,2-bis(2-amino thiophenol)ethane. The reactions of the ligand with different transition metal(II) salts under reflux system condition afforded a series of metal complexes such as Cu(II), Co(III), Ni(II) and Pd(II). Ligand and its complexes were characterized by a combination of elemental analysis, UV-vis spectroscopy, FT-IR, H-1 NMR, MS and TGA/DTA. The electrochemical properties of L and [Cu(L)] were investigated using cyclic voltammetry (CV) in the solutions of dimethyl sulfoxide (DMSO). The catalytic property of thio Schiff base ligand with Suzuki cross-coupling reactions were also determined with different substituted aryl halides in the presence of aryl boronic acid and Pd(AcO)(2) as catalyst. In addition, the fabrication of organic-inorganic hybrid devices using L and its Co(III), Ni(II) and Pd(II) complexes and their electrical properties have been reported. (C) 2011 Elsevier B.V. All rights reserved. |
|
dc.description.abstract |
C1 [Temel, Hamdi; Pasa, Salih] Dicle Univ, Dept Chem, Fac Educ, TR-21280 Diyarbakir, Turkey. |
|
dc.description.abstract |
[Ocak, Yusuf Selim] Dicle Univ, Dept Sci, Fac Educ, TR-21280 Diyarbakir, Turkey. |
|
dc.description.abstract |
[Yilmaz, Ismail] Tech Univ Istanbul, Dept Chem, TR-34469 Istanbul, Turkey. |
|
dc.description.abstract |
[Demir, Serpil; Ozdemir, Ismail] Univ Inonu, Dept Chem, Fac Sci & Art, TR-44280 Malatya, Turkey. |
|
dc.source |
SYNTHETIC METALS |
|
dc.title |
Synthesis, characterization, electrochemical behaviors and applications |
|
dc.title |
in the Suzuki-Miyaura cross-coupling reactions of N2S2O2 thio Schiff |
|
dc.title |
base ligand and its Cu(II), Co(III), Ni(II), Pd(II) complexes and their |
|
dc.title |
usage in the fabrication of organic-inorganic hybrid devices |
|